Effect of the nature of the salt on the reaction of sulfur dioxide with nonaqueous electrolytes

Journal Article · Wed Nov 09 23:00:00 EST 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6167765

Shembel', E M; Apostolova, R D; Es'kova, N I

Nonaqueous sulfur dioxide solutions are used as electrolytes in high-energy lithium-anode batteries. This paper reports the effect of salt type on the reaction between sulfur dioxide and component of a nonaqueous solution. They also studied the effect of sulfur dioxide content on solution conductivities and correlated them with the IR spectral characteristics. The aprotic solvents, which are widely used in nonaqueous batteries, were: propylene carbonate, acetonitrile, dimethyl sulfoxide, and dimethylformamide. The salts were lithium and tetrabutylammonium perchlorates.

• OSTI ID: 6167765
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 61:5; ISSN JAPUA
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
ABSORPTION SPECTRA
ACETONITRILE
ALKALI METAL COMPOUNDS
AMIDES
AMINES
AMMONIUM COMPOUNDS
AMMONIUM PERCHLORATES
CARBONIC ACID ESTERS
CHALCOGENIDES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
DISSOLUTION
DMSO
ELECTRIC BATTERIES
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
ELECTROCHEMICAL CELLS
ELECTROLYTES
ESTERS
HALOGEN COMPOUNDS
INFRARED SPECTRA
LITHIUM COMPOUNDS
LITHIUM PERCHLORATES
LITHIUM-SULFUR BATTERIES
MATERIALS TESTING
METAL-NONMETAL BATTERIES
NITRILES
OPTIMIZATION
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PERCHLORATES
PHYSICAL PROPERTIES
QUATERNARY COMPOUNDS
SOLVENTS
SPECTRA
SULFOXIDES
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
TESTING