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A transmission electron microscopy study of constituent-particle-induced corrosion in 7075-T6 and 2024-T3 aluminum alloys

Journal Article · · Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science
 [1];  [2];  [3]
  1. Lehigh Univ., Bethlehem, PA (United States). Dept. of Mechanical Engineering and Mechanics
  2. China Steel Corp., Kaohsiung (Taiwan, Province of China)
  3. Mobil Exploration and Producing Center, Farmers Branch, TX (United States). Material, Corrosion and Inspection Group

To better understand particle-induced pitting corrosion in aluminum alloys, thin foil specimens of 7075-T6 and 2024-T3 aluminum alloys, with identified constituent particles, were immersed in aerated 0.5M NaCl solution and then examined by transmission electron microscopy (TEM). The results clearly showed matrix dissolution around the iron- and manganese-containing particles (such as Al{sub 23}CuFe{sub 4}), as well as the Al{sub 2}Cu particles. While Al{sub 2}CuMg particles tended to dissolve relative to the matrix, limited local dissolution of the matrix was also observed around these particles. These results are consistent with scanning electron microscopy (SEM) observations of pitting corrosion and are discussed in terms of the electrochemical characteristics of the particles and the matrix.

Sponsoring Organization:
USDOE
OSTI ID:
616490
Journal Information:
Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science, Journal Name: Metallurgical and Materials Transactions. A, Physical Metallurgy and Materials Science Journal Issue: 4 Vol. 29; ISSN 1073-5623; ISSN MMTAEB
Country of Publication:
United States
Language:
English

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