Study of phase relationships with the MgO-CuO-Cu{sub 2}O-P{sub 2}O{sub 5} system
Journal Article
·
· Journal of the American Ceramic Society
OSTI ID:616478
- Oak Ridge National Lab., TN (United States). Chemical and Analytical Sciences Div.
The formation of the known compound Cu{sup +}Cu{sup 2+}Mg{sub 3}(PO{sub 4}){sub 3} by alternate reactions and its thermal stability were studied. The formation of solid solutions of the types Mg{sub 2{minus}x}Cu{sub x}P{sub 2}O{sub 7} and Mg{sub 3{minus}x}Cu{sub x}(PO{sub 4}){sub 2} was reexamined, mainly to aid in the identification of the products of decomposition of Cu{sup +}Cu{sup 2+}Mg{sub 3}(PO{sub 4}){sub 3}. X-ray diffractometry patterns of Mg{sub 2{minus}x}Cu{sub x}P{sub 2}O{sub 7} varied gradually in the range 0 {le} x {le} 2, which indicates complete miscibility.
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC05-96OR22464
- OSTI ID:
- 616478
- Journal Information:
- Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 2 Vol. 81; ISSN 0002-7820; ISSN JACTAW
- Country of Publication:
- United States
- Language:
- English
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