Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide
Patent
·
OSTI ID:6163438
A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.
- DOE Contract Number:
- W-31109-ENG-38
- Assignee:
- Dept. of Energy, Washington, DC (United States)
- Patent Number(s):
- US 5198589; A
- Application Number:
- PPN: US 7-874897
- OSTI ID:
- 6163438
- Country of Publication:
- United States
- Language:
- English
Similar Records
Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide
Rhodium catalyzed hydroformylation of internal olefins
Supercritical hydroformylations
Patent
·
Thu Dec 31 23:00:00 EST 1992
·
OSTI ID:868718
Rhodium catalyzed hydroformylation of internal olefins
Patent
·
Mon Nov 24 23:00:00 EST 1986
·
OSTI ID:7203799
Supercritical hydroformylations
Conference
·
Thu Nov 30 23:00:00 EST 1995
·
OSTI ID:126369
Related Subjects
02 PETROLEUM
020400* -- Petroleum-- Processing
ACYLATION
ALKENES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
CARBOXYLIC ACID SALTS
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
ELEMENTS
FORMATES
HYDROCARBONS
HYDROGEN
HYDROGENATION
ISOMERS
NONMETALS
OPTIMIZATION
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SUPERCRITICAL STATE
YIELDS
020400* -- Petroleum-- Processing
ACYLATION
ALKENES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
CARBOXYLIC ACID SALTS
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
ELEMENTS
FORMATES
HYDROCARBONS
HYDROGEN
HYDROGENATION
ISOMERS
NONMETALS
OPTIMIZATION
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SUPERCRITICAL STATE
YIELDS