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Reactivity of carbanions. XXV. Cleavage of dibenzhydryl ether under phase-transfer catalysis conditions

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6160799
; ; ;

Dibenzhydryl ether is cleaved under the conditions of phase-transfer catalysis in a system consisting of a solid powdered base and an organic phase with the formation of benzoquinone and diphenylmethane. The orders of effectiveness were established for the action of the bases, phase-transfer catalysts, and solvents in the reaction.

Research Organization:
M.V. Lomonosov Moscow State Univ. (USSR)
OSTI ID:
6160799
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:9; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
AMMONIUM COMPOUNDS
ANIONS
AROMATICS
BASES
BENZENE
CARBANIONS
CARBON COMPOUNDS
CARBONATES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHARGED PARTICLES
CHEMICAL REACTIONS
DISSOCIATION
ENERGY
ETHERS
GLYCOLS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXIDES
HYDROXY COMPOUNDS
IONS
ISOMERIZATION
LITHIUM COMPOUNDS
LITHIUM HYDROXIDES
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SOLVENTS
OXYGEN COMPOUNDS
POLYETHYLENE GLYCOLS
POLYMERS
POTASSIUM CARBONATES
POTASSIUM COMPOUNDS
POTASSIUM HYDROXIDES
QUATERNARY COMPOUNDS
SODIUM COMPOUNDS
SODIUM HYDROXIDES
SOLVENTS