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Acrylic esters in radiation polymerization

Journal Article · · High Energy Chem. (Engl. Transl.); (United States)
OSTI ID:6160259
; ;

The radiation behavior of (meth)acrylic esters of varying structure was studied. It was shown that in radiation polymerization, in contrast to thermal polymerization, the structure of the ester part can significantly affect the reaction rate and capacity for polymerization in the presence of oxygen. The experimental data are explained from the point of view of consideration of nonvalence effects of the substitutent on the reactivity of the double bond.

Research Organization:
L. Ya. Karpov Scientific-Research Institute of Physical Chemistry (USSR)
OSTI ID:
6160259
Journal Information:
High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 21:5; ISSN HIECA
Country of Publication:
United States
Language:
English

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ACRYLIC ACID ESTERS
ACTIVATION ENERGY
AIR
ALCOHOLS
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BINDING ENERGY
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACID SALTS
CHEMICAL BONDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COBALT 60
COBALT ISOTOPES
DOSE RATES
ELECTROMAGNETIC RADIATION
ELEMENTS
ENERGY
ESTERS
FLUIDS
GAMMA RADIATION
GASES
GLYCOLS
HYDROXY COMPOUNDS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
IONIZING RADIATIONS
IRRADIATION
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
METHACRYLATES
MINUTES LIVING RADIOISOTOPES
NITROGEN
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC POLYMERS
POLYACRYLATES
POLYMERIZATION
POLYMERS
POLYVINYLS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADIOISOTOPES
REACTION KINETICS
TEMPERATURE EFFECTS
YEARS LIVING RADIOISOTOPES