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Optical activity of monochelate complexes of platinum(II) with cyclic L-amino acids and (+)-methylbenzylamine (in Russian)

Journal Article · · Sov. J. Coordinat. Chem.; (United States)
OSTI ID:6158259
Three new complex compounds of platinum(II) have been synthesized: trans-(N,N)-(Pt(MBA)(pro)Cl), (Pt(MBA)/sub 2/(hyp))Cl, and (Pt(NH/sub 3/)/sub 2/(pro))Cl, where pro and hyp stand for coordinated bidentate anions of L-proline and L-hydroxyproline, and MBA stands for coordinated monodentate (+)-methylbenzylamine. The structurally similar complex compounds have been characterized by their IR and electronic absorption spectra and their circular dichroism spectra in the dissolved and polycrystalline states. A proposed assignment of the bands in the spectra of the complex compounds has been given.
Research Organization:
Novosibirsk State Univ., USSR
OSTI ID:
6158259
Journal Information:
Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 12:2; ISSN SJCCD
Country of Publication:
United States
Language:
Russian

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