Advanced coal liquefaction research. Technical progress report, January 1-April 30, 1984
The significant improvement in product quality reported last year for bituminous and subbituminous coals has been demonstrated with lignite. As discussed previously, use of a vapor-phase hydrotreater and recycle of all heavy distillate advances the SRC II process far beyond that envisioned for the original demonstration plant. As with the other coal ranks, all net distillate product from the lignite boils below 345/sup 0/C (653/sup 0/F) and has a nitrogen concentration on the order of 1 ppM. It was also confirmed that the Texas Big Brown lignite can be processed successfully in this mode without added catalyst. Both subbituminous Belle Ayr and bituminous Illinois No. 6 coals were processed in an integrated two-stage mode, without depressurization or solids separation between stages. Operation was relatively smooth with a fixed-bed second stage employing a high-void-volume (star-shaped) catalyst support, which was operated upflow. There was no evidence that H/sub 2/S addition improved yields with Belle Ayr coal and added pyrite or that H/sub 2/S could be used in place of pyrite to catalyze the reaction. 84 figures, 6 tables.
- Research Organization:
- Gulf Research and Development Co., Shawnee Mission, KS (USA)
- DOE Contract Number:
- AC22-82PC50001
- OSTI ID:
- 6153278
- Report Number(s):
- DOE/PC/50001-31; ON: DE85006940
- Resource Relation:
- Other Information: Portions are illegible in microfiche products. Original copy available until stock is exhausted
- Country of Publication:
- United States
- Language:
- English
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Advanced coal-liquefaction research. Technical progress report, August 1, 1982-December 31, 1982
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Related Subjects
COAL LIQUIDS
HYDROGENATION
RECYCLING
SRC-II PROCESS
CATALYSTS
YIELDS
ACTIVATION ANALYSIS
BITUMINOUS COAL
CATALYTIC EFFECTS
COAL LIQUEFACTION
EXPERIMENTAL DATA
FLOWSHEETS
HYDROGEN SULFIDES
INFRARED SPECTRA
LIGNITE
LIQUID COLUMN CHROMATOGRAPHY
PYRITE
SUBBITUMINOUS COAL
TEMPERATURE EFFECTS
TSL PROCESS
BLACK COAL
BROWN COAL
CARBONACEOUS MATERIALS
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
CHROMATOGRAPHY
COAL
DATA
DIAGRAMS
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUELS
HYDROGEN COMPOUNDS
INFORMATION
IRON COMPOUNDS
IRON SULFIDES
LIQUEFACTION
LIQUIDS
MATERIALS
MINERALS
NUMERICAL DATA
SEPARATION PROCESSES
SPECTRA
SULFIDE MINERALS
SULFIDES
SULFUR COMPOUNDS
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPOUNDS
010405* - Coal
Lignite
& Peat- Hydrogenation & Liquefaction