IR spectra of methanol and dimethyl ether adsorbed on high-silica zeolites

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6152835

Khashagul'gova, N S; Khadzhiev, S N; Kubasov, A A

The results of methanol adsorption on mordenite are evidence for the formation of aliphatic chains. On ultrasil zeolite, methanol adsorption at room temperature causes methoxylation of the surface; at 523/sup 0/K and above, it forms carboxy structures that are apparently intermediates in the conversion to hydrocarbons. Analogous structures were observed during the adsorption of dimethyl ether. 5 references, 3 figures.

• Research Organization: Moscow State Univ., USSR
• OSTI ID: 6152835
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 24:5; Other Information: Translated from Kinet. Katal.; 24: No. 5, 1261-1265(Sep-Oct 1983)
• Country of Publication: United States
• Language: English

Related Subjects

10 SYNTHETIC FUELS
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
METHANOL
CHEMISORPTION
STRUCTURAL CHEMICAL ANALYSIS
METHYL ETHER
MORDENITE
SORPTIVE PROPERTIES
ABSORPTION SPECTROSCOPY
CATALYSTS
DATA ANALYSIS
EXPERIMENTAL DATA
HIGH TEMPERATURE
INFRARED SPECTRA
MEDIUM TEMPERATURE
REACTION INTERMEDIATES
SAMPLE PREPARATION
TEMPERATURE DEPENDENCE
ALCOHOLS
CHEMICAL REACTIONS
DATA
ETHERS
HYDROXY COMPOUNDS
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MINERALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
SEPARATION PROCESSES
SILICATE MINERALS
SORPTION
SPECTRA
SPECTROSCOPY
SURFACE PROPERTIES
ZEOLITES
090210* - Alcohol Fuels- Properties- (1976-1989)
400201 - Chemical & Physicochemical Properties