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Synthesis, structure, and spectroscopic and magnetic properties of lutetium(III) phthalocyanine derivatives: LuPc/sub 2/ x CH/sub 2/Cl/sub 2/ and (LuPc(OAc)(H/sub 2/O)/sup 2/) H/sub 2/O x 2CH/sub 3/OH

Journal Article · · Inorg. Chem.; (United States)
DOI:https://doi.org/10.1021/ic00214a016· OSTI ID:6149632
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The bis(phthalocyaninato)lutetium(III) derivative LuPc/sub 2/ x CH/sub 2/Cl/sub 2/ (1, LuC/sub 65/H/sub 34/N/sub 16/Cl/sub 2/) and the (phthalocyaninato)lutetium(III) complex (LuPc(OAc)(H/sub 2/O)/sub 2/) x H/sub 2/O x 2CH/sub 3/OH (2, LuC/sub 36/H/sub 33/N/sub 8/O/sub 7/) were synthesized in boiling 1-hexanol with use of lutetium(III) acetate and 1,2-dicyanobenzene in the presence of 1,8-diazabicyclo(5.4.0)undec-7-ene and purified by chromatography. The visible spectroscopic properties are reported for both complexes. 1 crystallizes in the orthorhombic system with a = 28.242 (9) A, b = 22.877 (8) A, c = 8.050 (4) A, Z = 4, and space group Pnma. 2 belongs to the monoclinic system with a = 12.033 (3) A, b = 20.807 (6) A, c = 14.011 (3) A, ..beta.. = 95.34 (2)/sup 0/, space group P2/sub 1//n, and Z = 4. 1 is a sandwich type complex in which the lutetium atom is eightfold coordinated by the isoindole nitrogens (N/sub iso/) of two staggered phthalocyanine rings. 28 references, 5 figures, 6 tables.
Research Organization:
Universite Louis Pasteur, Strasbourg Cedex, France
OSTI ID:
6149632
Journal Information:
Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 24:20; ISSN INOCA
Country of Publication:
United States
Language:
English

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Related Subjects

36 MATERIALS SCIENCE
360102* -- Metals & Alloys-- Structure & Phase Studies
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
BOND ANGLE
BOND LENGTHS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALLOGRAPHY
DATA
DERIVATIZATION
DIFFRACTION
DIMENSIONS
EXPERIMENTAL DATA
INFORMATION
LENGTH
LUTETIUM COMPLEXES
MOLECULAR STRUCTURE
NUMERICAL DATA
RARE EARTH COMPLEXES
SCATTERING
SPECTRA
SYNTHESIS
ULTRAVIOLET SPECTRA
X-RAY DIFFRACTION