Nuclear quadrupole structure of potassium hydroxide in the 32 GHz microwave region

Journal Article · Tue Sep 15 04:00:00 EDT 1987 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.452973· OSTI ID:6147735

Raw, T T; Yamamura, T; Gillies, C W

A high temperature Stark and radiofrequency-microwave double resonance spectrometer was used to observe the nuclear quadrupole structure of the J = 2reverse arrow1 transition of TZKOH in a number of vibrational states. First order analysis of the hyperfine components gave nuclear quadrupole coupling constants of eQq = -7.23 (29) MHz for the (000) state, eQq = -7.16 (33) MHz for the (100) state, and eQq = -7.29 (37) MHz for the (01 0) state.

• Research Organization: Department of Chemistry, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
• OSTI ID: 6147735
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 87:6; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKALI METAL COMPOUNDS
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
HYDROGEN COMPOUNDS
HYDROXIDES
HYPERFINE STRUCTURE
MICROWAVE SPECTRA
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
POTASSIUM HYDROXIDES
QUADRUPOLE MOMENTS
SPECTRA
STARK EFFECT