The leaching behavior of borate waste glass SL-1

Journal Article · Fri Jan 01 04:00:00 EST 1999 · Waste Management

DOI:https://doi.org/10.1016/S0956-053X(99)00196-8· OSTI ID:6145771

Sheng, J ^[1]; Luo, S; Tang, B ^[2]

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1. Kyoto Univ., Osaka (Japan)
2. China Inst. of Atomic Energy, Beijing (China)

Vitrification is an attractive approach for treatment of the borate waste from nuclear power plants. SL-1 glass is a suitable borosilicate glass form to solidify the borate waste containing relatively high quantities of B and Na. The leaching behavior of SL-1 glass in deionized water has been investigated. Compared to the HLW-glass, the network structure of SL-1 glass is weak. It was found that the ion-exchange reactions dominated the glass corrosion process with water in low temperature leading conditions. The ion-exchange and network hydrolysis reactions together controlled the glass dissolution in high temperature leaching conditions. There was a peak in leach rate at about 70 C and a valley at about 100 C. The surface layer thickness was about 25 [micro]m. Na was almost totally depleted in the surface layer. At low temperature, the glass corrosion increases with leaching time. The glass corrosion remains about constant with leaching time at 90 C. The surface layer formed at 90 C is protective, which is less porous than the surface layer formed at 40 and 70 C.

• OSTI ID: 6145771
• Journal Information: Waste Management, Journal Name: Waste Management Vol. 19:6; ISSN WAMAE2; ISSN 0956-053X
• Country of Publication: United States
• Language: English

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
320305* -- Energy Conservation
Consumption
& Utilization-- Industrial & Agricultural Processes-- Industrial Waste Management
ALKALI METALS
BORATES
BORON
BORON COMPOUNDS
DISSOLUTION
ELEMENTS
GLASS
HIGH-LEVEL RADIOACTIVE WASTES
LEACHING
MANAGEMENT
MATERIALS
METALS
NUCLEAR FACILITIES
NUCLEAR POWER PLANTS
OXYGEN COMPOUNDS
POWER PLANTS
PROCESSING
RADIOACTIVE MATERIALS
RADIOACTIVE WASTE MANAGEMENT
RADIOACTIVE WASTE PROCESSING
RADIOACTIVE WASTES
SEMIMETALS
SEPARATION PROCESSES
SODIUM
THERMAL POWER PLANTS
VITRIFICATION
WASTE MANAGEMENT
WASTE PROCESSING
WASTES