The /sup 31/P and /sup 119/Sn NMR of adducts of methyltintrihalides with bidentate tertiary phosphines

Journal Article · Tue Oct 01 04:00:00 EDT 1985 · Dokl. Chem. (Engl. Transl.); (United States)

OSTI ID:6143789

Yashina, N S; Gefel', E I; Petrosyan, V S; Reutov, O A

As part of an investigation of the spatial and electronic structure of complexes of inorganic derivatives of Sn(IV) with various heteroatomic electron donors, the authors have studied the reaction of MeSnX/sub 3/ (X = Cl, Br) with the tertiary, bidentate phosphines, Ph/sub 2/P(CH/sub 2/) /SUB n/ PPh/sub 2/ (n=1-4). In this paper on the spatial and electronic structure of complexes of tin with phosphines they have made use of /sup 31/P and /sup 119/Sn NMR spectroscopy. To confirm the stoichiometry of the complexes formed, they were separated from methylene chloride by addition of petroleum ether.

• Research Organization: M.V. Lomonosov Moscow State Univ., Moscow
• OSTI ID: 6143789
• Journal Information: Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 281:4; ISSN DKCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
ADDUCTS
BROMIDES
BROMINE COMPOUNDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DAYS LIVING RADIOISOTOPES
DERIVATIZATION
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
ETHERS
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
RADIOISOTOPES
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STOICHIOMETRY
TIN 119
TIN COMPLEXES
TIN ISOTOPES