skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state

Abstract

Solid-state cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectra have been recorded on chlorophyll a-water aggregates, methyl pyrochlorophyllide a, and methyl pyropheophorbide a. Spectra have also been collected under a decoupling regime in which resonances of certain hydrogen-bearing carbon atoms are suppressed. These observations are used to assign the solid-state spectra. 18 references, 2 figures, 1 table.

Authors:
; ; ;
Publication Date:
Research Org.:
Medical College of Wisconsin, Milwaukee
OSTI Identifier:
6138399
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Journal Article
Resource Relation:
Journal Name: Proc. Natl. Acad. Sci. U.S.A.; (United States); Journal Volume: 81
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES; CHLOROPHYLL; NMR SPECTRA; CARBON 13; CHEMICAL SHIFT; EXPERIMENTAL DATA; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; CARBON ISOTOPES; CARBOXYLIC ACIDS; DATA; EVEN-ODD NUCLEI; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; INFORMATION; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; NUCLEI; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYTOCHROMES; PIGMENTS; PORPHYRINS; PROTEINS; RESONANCE; SPECTRA; STABLE ISOTOPES; 550201* - Biochemistry- Tracer Techniques

Citation Formats

Brown, C.E., Spencer, R.B., Burger, V.T., and Katz, J.J. Cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state. United States: N. p., 1984. Web. doi:10.1073/pnas.81.2.641.
Brown, C.E., Spencer, R.B., Burger, V.T., & Katz, J.J. Cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state. United States. doi:10.1073/pnas.81.2.641.
Brown, C.E., Spencer, R.B., Burger, V.T., and Katz, J.J. Sun . "Cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state". United States. doi:10.1073/pnas.81.2.641.
@article{osti_6138399,
title = {Cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state},
author = {Brown, C.E. and Spencer, R.B. and Burger, V.T. and Katz, J.J.},
abstractNote = {Solid-state cross-polarization/magic-angle sample-spinning /sup 13/C NMR spectra have been recorded on chlorophyll a-water aggregates, methyl pyrochlorophyllide a, and methyl pyropheophorbide a. Spectra have also been collected under a decoupling regime in which resonances of certain hydrogen-bearing carbon atoms are suppressed. These observations are used to assign the solid-state spectra. 18 references, 2 figures, 1 table.},
doi = {10.1073/pnas.81.2.641},
journal = {Proc. Natl. Acad. Sci. U.S.A.; (United States)},
number = ,
volume = 81,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1984},
month = {Sun Jan 01 00:00:00 EST 1984}
}