Rearrangement of oxime allyl ethers under electronic impact
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6136603
A 3,3-sigmatropic rearrangement followed by the elimination of the NO particle is observed in the molecular ions of aldoxime allyl ethers. In the ethers of ketoximes 2,3-migration of the allyl group predominates and leads to the formation of (M - OH)/sup +/ ions characteristic of aliphatic N-oxides.
- Research Organization:
- A.A. Zhdanov Leningrad State Univ., USSR
- OSTI ID:
- 6136603
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:11; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
AMINES
BEAMS
CHARGED PARTICLES
CHROMATOGRAPHY
COLLISIONS
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DISSOCIATION
ELECTRON BEAMS
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
ETHERS
HYDRAZONES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
IONIZATION
IONS
J-J COUPLING
LEPTON BEAMS
MASS SPECTRA
MOLECULAR IONS
MOLECULAR STRUCTURE
MOLECULE COLLISIONS
MULTIPLETS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIMES
PARTICLE BEAMS
SEPARATION PROCESSES
SPECTRA
TRIPLETS
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
AMINES
BEAMS
CHARGED PARTICLES
CHROMATOGRAPHY
COLLISIONS
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DISSOCIATION
ELECTRON BEAMS
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
ETHERS
HYDRAZONES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
IONIZATION
IONS
J-J COUPLING
LEPTON BEAMS
MASS SPECTRA
MOLECULAR IONS
MOLECULAR STRUCTURE
MOLECULE COLLISIONS
MULTIPLETS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIMES
PARTICLE BEAMS
SEPARATION PROCESSES
SPECTRA
TRIPLETS