Reaction of alpha-gem-trichlorocarbonyl compounds with conjugated alkadienes

Journal Article · Thu Apr 10 04:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6136595

Startsev, V V; Zubritskii, L M; Gorbunkov, V D; Petrov, A A

Chloral and gem-trichloroacetone add to 1,3-alkadienes in the presence of copper(I) chloride with the formation of the corresponding ..gamma..,delta-unsaturated ..cap alpha..,..cap alpha..epsilon-trichlorocarbonyl compounds as mixtures of the E and Z isomers in a ratio in the order of 85:15. The reaction takes place under mild conditions and gives a high yield of the final products.

• Research Organization: Lensovet Leningrad Technological Institute, USSR
• OSTI ID: 6136595
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:11; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETONE
BINDING ENERGY
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINE COMPOUNDS
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
COUPLING
COUPLING CONSTANTS
DIENES
ENERGY
ENERGY LEVELS
EXCITED STATES
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
KETONES
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYENES
SPECTRA
STEREOCHEMISTRY
TRANSITION ELEMENT COMPOUNDS
VALENCE
VIBRATIONAL STATES
YIELDS