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U.S. Department of Energy
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Progress in evaluation of radionuclide geochemical information developed by DOE high-level nuclear waste repository site projects: report for April-June 1984. Volume 3

Technical Report ·
OSTI ID:6135211

Geochemical information relevant to the retention of radionuclides by candidate high-level waste repositories being developed by Department of Energy (DOE) projects is being evaluated by Oak Ridge National Laboratory (ORNL) for the Nuclear Regulatory Commission (NRC). During this report period, the project has evaluated radionuclide sorption and solubility values applicable to the candidate repository site in the Columbia River basalts at the Hanford Reservation. The removal of technetium from pertechnetate-traced groundwater by McCoy Canyon basalt under anoxic redox conditions (air excluded) at 27/sup 0/C was found to be sensitive to the ground-water composition. Sorption of uranium from groundwater by McCoy Canyon basalt under oxic redox conditions at 60/sup 0/C showed low sorption ratios (1.8 to 2.4 L/kg) similar to those previously obtained at 27/sup 0/C. The average sorption ratio for strontium in groundwater onto McCoy Canyon basalt under oxic redox conditions at 27/sup 0/C was 225 L/kg. Column chromatographic experiments with neptunium in groundwater to measure retardation factors at temperatures from 25 to 80/sup 0/C gave calculated sorption ratio values that were in good agreement with the values previously obtained in batch contact tests. 27 references, 5 figures, 4 tables.

Research Organization:
Oak Ridge National Lab., TN (USA)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
6135211
Report Number(s):
NUREG/CR-3851-Vol.3; ORNL/TM-9191/V3; ON: TI85003282
Country of Publication:
United States
Language:
English