Eigenchannel quantum-defect theory of open-shell atoms. II. Calculation of 3p/sup 4/( /sup 3/P)ns Rydberg spectra of the chlorine atom
Journal Article
·
· Phys. Rev. A; (United States)
Rydberg spectra of the chlorine atom 3s/sup 2/3p/sup 4/( /sup 3/P)ns, J = (1/2), (3/2), and (5/2), are calculated by use of an eigenchannel quantum-defect method. The results indicate that the channel interactions due to electrostatic and spin-orbit potentials are weak. The effect due to channel interaction of the 3s3p/sup 6/ configuration is completely negligible. Agreement with emission data is excellent (< or approx. =0.2% accuracy except for the lowest n = 4 levels). Autoionization resonances are predicted.
- Research Organization:
- Argonne National Laboratory, Argonne, Illinois 60439
- OSTI ID:
- 6131493
- Journal Information:
- Phys. Rev. A; (United States), Journal Name: Phys. Rev. A; (United States) Vol. 31:3; ISSN PLRAA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Eigenchannel quantum-defect theory of open-shell atoms. I. Autoionization resonances and eigenphase shifts of chlorine
Photoionization of Cl+ from the 3s23p4 3P2,1,0 and the 3s23p4 1D2,1S0 states in the energy range 19–28 eV
Relativistic Multireference Many-body Perturbation Theory for Open-shell Ions with Multiple Valence Shell Electrons: the Transition Rates and Lifetimes of the Excited Levels in Chlorinelike Fe X
Journal Article
·
Thu Feb 28 23:00:00 EST 1985
· Phys. Rev. A; (United States)
·
OSTI ID:5992097
Photoionization of Cl+ from the 3s23p4 3P2,1,0 and the 3s23p4 1D2,1S0 states in the energy range 19–28 eV
Journal Article
·
Sun Oct 30 20:00:00 EDT 2016
· Monthly Notices of the Royal Astronomical Society
·
OSTI ID:1523814
Relativistic Multireference Many-body Perturbation Theory for Open-shell Ions with Multiple Valence Shell Electrons: the Transition Rates and Lifetimes of the Excited Levels in Chlorinelike Fe X
Journal Article
·
Wed Sep 30 00:00:00 EDT 2009
· Journal of Physics B: Atomic Molecular and Optical Physics, vol. 43, no. 7, March 19, 2010, pp. 074022
·
OSTI ID:975222
Related Subjects
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ATOMS
AUTOIONIZATION
CHLORINE
CONFIGURATION MIXING
EIGENSTATES
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY LEVELS
EXCITED STATES
HALOGENS
INTERACTIONS
IONIZATION
NONMETALS
P STATES
PHASE SHIFT
RESONANCE
RYDBERG STATES
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ATOMS
AUTOIONIZATION
CHLORINE
CONFIGURATION MIXING
EIGENSTATES
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY LEVELS
EXCITED STATES
HALOGENS
INTERACTIONS
IONIZATION
NONMETALS
P STATES
PHASE SHIFT
RESONANCE
RYDBERG STATES