eta. sup 2 - and. eta. sup 2 (Se)-. mu. sub 2 -selenophene (Sel) coordination in Cp*(CO) sub 2 Re(2,3-. eta. sup 2 -Sel) and Cp*(CO) sub 2 Re(. eta. sup 2 (Se)-. mu. sub 2 -Sel)(W(CO) sub 4 (PPh sub 3 ))

Journal Article · Wed Oct 10 04:00:00 EDT 1990 · Journal of the American Chemical Society; (USA)

DOI:https://doi.org/10.1021/ja00177a060· OSTI ID:6130508

Choi, Moon-Gun; Angelici, R J ^[1]

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1. Ames Lab., IO (USA)

In connection with the authors interest in the mechanism(s) of the hydrodesulfurization (HDS) of thiophenes on heterogeneous catalyst. They have explored various modes of thiophene (T) coordination in transition-metal complexes. In a previous report, they described the synthesis of the complex Cp*(CO){sub 2}Re(T) in which the thiophene (T) was S-coordinated to the rhenium. In this communication, they report the analogous selenophene (Sel) complex Cp*(CO){sub 2}Re(Sel) in which the selenophene is 2,3-{eta}{sup 2}-coordinated to the metal.

• DOE Contract Number: W-7405-ENG-82
• OSTI ID: 6130508
• Journal Information: Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 112:21; ISSN 0002-7863; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400* -- Petroleum-- Processing
CATALYSIS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DATA
DESULFURIZATION
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HETEROGENEOUS CATALYSIS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
RHENIUM COMPLEXES
SELENIUM COMPLEXES
SYNTHESIS
THIOPHENE
TRANSITION ELEMENT COMPLEXES