Novel phosphido-bridged cations (M sub 2 (CO) sub 8 (. mu. -PPh sub 2 ))BF sub 4 (M = Fe, Ru): Synthesis, reactivity, and X-ray structure of an isoelectronic and structural analogue of Ru sub 2 (CO) sub 9
Journal Article
·
· Organometallics; (United States)
- Univ. of Waterloo, Ontario (Canada)
The cationic 34-electron phosphido-bridged binuclear complexes (M{sub 2}(CO){sub 8}(PPh{sub 2}))BF{sub 4} (1, M = Fe; 2, M = Ru) have been synthesized and their electrophilic reactivities explored. An X-ray analysis of 2 has revealed it to be a structural analogue of the isoelectronic but incompletely characterized Ru{sub 2}(CO){sub 9}.
- OSTI ID:
- 6110012
- Journal Information:
- Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 9:10; ISSN 0276-7333; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
Similar Records
Chemical transformations on phosphido-bridged clusters. Methyne, methylene transfer, and ketene forming reactions involving the. mu. methylene cluster Ru/sub 3/(CO)/sub 7/(. mu. -CH/sub 2/)/. mu. /sub 3/-eta/sup 3/-CH/sub 2/ =C=C(i-Pr)/(. mu. -PPh/sub 2/). X-ray structures of (. mu. -H)Ru/sub 3/(CO)/sub 7//. mu. /sub 3/-eta/sup 4/-CH=C(i-Pr)C=CH/sub 2//(. mu. -PPH/sub 2/) and Ru/sub 3/(CO)/sub 6/(. mu. -CO)/. mu. /sub 3/-eta/sup 4/-CH/sub 2/=C(i-Pr)C=CH/sub 2//(PPh/sub 3/)(. mu. -PPH/sub 2/)
Chemical transformations on phosphido- and phosphinidene-bridged ruthenium clusters
The cluster anion (HRu sub 3 (CO) sub 8 (. mu. -PPh sub 2 ) sub 2 ) sup minus as a building block for the assembly of bimetallic tetranuclear clusters: Synthesis, structure, fluxionality, and reactivity. Syntheses and structures of (H sub 2 Ru sub 3 Rh(. mu. -CO)(CO) sub 6 (PPh sub 3 ) sub 2 (. mu. -PPh sub 2 )(PPhC sub 6 H sub 4 )) and (H sub 2 Ru sub 3 Ir(. mu. -CO)(CO) sub 7 (PPh sub 3 )(. mu. -PPh sub 2 )(PPhC sub 6 H sub 4 ))
Journal Article
·
Thu Dec 31 23:00:00 EST 1987
· Organometallics; (United States)
·
OSTI ID:7148476
Chemical transformations on phosphido- and phosphinidene-bridged ruthenium clusters
Thesis/Dissertation
·
Mon Dec 31 23:00:00 EST 1990
·
OSTI ID:5517754
The cluster anion (HRu sub 3 (CO) sub 8 (. mu. -PPh sub 2 ) sub 2 ) sup minus as a building block for the assembly of bimetallic tetranuclear clusters: Synthesis, structure, fluxionality, and reactivity. Syntheses and structures of (H sub 2 Ru sub 3 Rh(. mu. -CO)(CO) sub 6 (PPh sub 3 ) sub 2 (. mu. -PPh sub 2 )(PPhC sub 6 H sub 4 )) and (H sub 2 Ru sub 3 Ir(. mu. -CO)(CO) sub 7 (PPh sub 3 )(. mu. -PPh sub 2 )(PPhC sub 6 H sub 4 ))
Journal Article
·
Tue May 01 00:00:00 EDT 1990
· Organometallics; (USA)
·
OSTI ID:6518962
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
BORON COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
IONS
IRON COMPLEXES
LITHIUM COMPOUNDS
MOLECULAR STRUCTURE
NMR SPECTRA
OXIDES
OXYGEN COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
BORON COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
IONS
IRON COMPLEXES
LITHIUM COMPOUNDS
MOLECULAR STRUCTURE
NMR SPECTRA
OXIDES
OXYGEN COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION