Cesium cation ordering in the Mo sub 6 P sub 10 O sub 38 framework: Synthesis and structure of Cs sub 4 Mo sub 6 P sub 10 O sub 38
Journal Article
·
· Journal of Solid State Chemistry; (USA)
- Exxon Research and Engineering Co., Annandale, NJ (USA)
Reaction of Cs{sub 2}MoO{sub 4}, MoO{sub 3}, P{sub 2}O{sub 5}, and Mo at 950{degree}C gives a mixture of the title compound and Cs{sub 3}Mo{sub 6}P{sub 10}O{sub 38} as the major products. The compound Cs{sub 4}Mo{sub 6}P{sub 10}O{sub 38} crystallizes in the monoclinic space group P2{sub 1}/m with a = 9.659(2), b = 14.404(2), c = 6.446(2) {angstrom}, and {beta} = 105.58(2){degree}. Important structural features include corner-sharing MoO{sub 6} octahedra containing Mo{sup 4+}, isolated octahedra containing Mo{sup 3+}, P{sub 2}O{sub 7}, and PO{sub 4} groups, and one-dimensional tunnels filled with Cs{sup +} cations.
- OSTI ID:
- 6106907
- Journal Information:
- Journal of Solid State Chemistry; (USA), Journal Name: Journal of Solid State Chemistry; (USA) Vol. 89:1; ISSN 0022-4596; ISSN JSSCB
- Country of Publication:
- United States
- Language:
- English
Similar Records
Layer and tunnel structures in new molybdenophosphates: Cs/sub 2/Mo/sub 4/P/sub 6/O/sub 26/ and M/sub 4/Mo/sub 8/P/sub 12/O/sub 52/ (M = Cs, Rb, K, Tl)
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Journal Article
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· J. Solid State Chem.; (United States)
·
OSTI ID:6198478
A novel Mo(V) oligophosphate built up of di- and triphosphate groups: Cs(MoO){sub 4}(P{sub 2}O{sub 7}){sub 2}(P{sub 3}O{sub 10})
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Tue Aug 15 00:00:00 EDT 2006
· Journal of Solid State Chemistry
·
OSTI ID:20905392
Parallel, segregated Cs sup + - and K sup + -filled one-dimensional tunnels in Cs sub 2 K sub 2 Mo sub 8 P sub 12 O sub 52
Journal Article
·
Tue Oct 31 23:00:00 EST 1989
· Journal of Solid State Chemistry; (USA)
·
OSTI ID:7247498
Related Subjects
36 MATERIALS SCIENCE
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CESIUM PHOSPHATES
CHEMICAL PREPARATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
INFORMATION
LATTICE PARAMETERS
MEASURING METHODS
MOLYBDENUM COMPOUNDS
MOLYBDENUM PHOSPHATES
MONOCLINIC LATTICES
NUMERICAL DATA
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SPACE GROUPS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CESIUM PHOSPHATES
CHEMICAL PREPARATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
INFORMATION
LATTICE PARAMETERS
MEASURING METHODS
MOLYBDENUM COMPOUNDS
MOLYBDENUM PHOSPHATES
MONOCLINIC LATTICES
NUMERICAL DATA
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SPACE GROUPS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS