Lattice effects observed by the isotope-difference pair density function of the YBa[sub 2][number sign]63/65Cu[sub 3]O[sub 6. 92] superconductor
- Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)
- Department of Physics, Northern Illinois University, DeKalb, Illinois 60115 (United States)
The local lattice effects in the YBa[sub 2]Cu[sub 3]O[sub 6.92] superconductor were characterized by the neutron differential pair density function (DPDF) analysis. The DPDF provides an atom specific PDF, enabling the distinction between overlapping atom pair correlations in complicated systems. It utilizes the contrast in the scattering amplitude enhanced by the different neutron scattering lengths for [sup 63]Cu and [sup 65]Cu in two isotopically pure samples with identical compositions. Significant structural distortions are observed in the superconducting planes, in association with the plane copper (Cu2). A bifurcation of the Cu2 to apical oxygen (O4) pair correlations is evident which is temperature dependent. This effect originates from distortions along the [ital c] axis of the crystal of the Cu2 ions and not of the O4, as no distortions are observed in association with the connecting pair, the Cu1 (chain)-O4. Secondary lattice anharmonicities in the chains are also seen, arising mostly from defects in the vicinity of oxygen vacancies. [copyright] [ital 1999] [ital The American Physical Society]
- OSTI ID:
- 6104728
- Journal Information:
- Physical Review, B: Condensed Matter, Vol. 60:10; ISSN 0163-1829
- Country of Publication:
- United States
- Language:
- English
Similar Records
The axial oxygen atom and superconductivity in YBa sub 2 Cu sub 3 O sub 7
Superconducting Phase Diagram of the Yttrium, Barium, and YBa-core in YBa{sub 2}Cu{sub 3}O{sub 7–δ} by an Ising Model
Related Subjects
ANHARMONIC CRYSTALS
BARIUM COMPOUNDS
BARIUM OXIDES
CHAINS
COPPER 63
COPPER 65
COPPER OXIDES
CRYSTAL STRUCTURE
HIGH-TC SUPERCONDUCTORS
ISOTOPE EFFECTS
LATTICE PARAMETERS
NEUTRON DIFFRACTION
SUPERCONDUCTIVITY
YTTRIUM COMPOUNDS
YTTRIUM OXIDES
ALKALINE EARTH METAL COMPOUNDS
CHALCOGENIDES
COHERENT SCATTERING
COPPER COMPOUNDS
COPPER ISOTOPES
CRYSTALS
DIFFRACTION
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
INTERMEDIATE MASS NUCLEI
ISOTOPES
NUCLEI
ODD-EVEN NUCLEI
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
SCATTERING
STABLE ISOTOPES
SUPERCONDUCTORS
TRANSITION ELEMENT COMPOUNDS
TYPE-II SUPERCONDUCTORS
360204* - Ceramics
Cermets
& Refractories- Physical Properties
360202 - Ceramics
Cermets
& Refractories- Structure & Phase Studies