High-temperature determination of the rate coefficient for the reaction H/sub 2/ + CN. -->. H + HCN

Journal Article · Sat Jan 01 04:00:00 EST 1983 · Int. J. Chem. Kinet.; (United States)

DOI:https://doi.org/10.1002/kin.550150907· OSTI ID:6103200

Szekely, A; Hanson, R K; Bowman, C T

The rate coefficient of the reaction H/sub 2/ + CN ..-->.. H + HCN has been determined in the temperature range of 2700-3500 K using a shock tube technique. C/sub 2/N/sub 2/-H/sub 2/Ar mixtures were heated behind incident shock waves and the early-time CN history was monitored using broad-band absorption spectroscopy. An expression is given for the rate coefficient, and results from this expression are in good agreement with extrapolations of previously published low-temperature results.

• Research Organization: Stanford Univ., CA
• DOE Contract Number: AM03-76SF00326
• OSTI ID: 6103200
• Journal Information: Int. J. Chem. Kinet.; (United States), Journal Name: Int. J. Chem. Kinet.; (United States) Vol. 15; ISSN IJCKB
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ANIONS
CHARGED PARTICLES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYANIDES
DATA
ELEMENTS
EXPERIMENTAL DATA
HYDROGEN
INFORMATION
IONS
KINETICS
NONMETALS
NUMERICAL DATA
REACTION KINETICS
SHOCK TUBES