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U.S. Department of Energy
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High resolution electron energy loss studies of surface vibrations: Progress report, July 1, 1988--June 20, 1989

Technical Report ·
DOI:https://doi.org/10.2172/6099429· OSTI ID:6099429

New experimental investigations of surface vibrational properties of materials with high-resolution electron energy loss spectroscopy (EELS) are reported. The effort has focused on surface phonon dispersion measurements for copper (111) and ultrathin epitaxial films of nickel and cobalt grown on a copper (001) substrate. Data and analysis of several surface modes and resonances on Cu (111) is consistent with a modest (15%) softening of the intraplanar force constant between surface atoms. For epitaxial thin films of a few monolayers thickness of nickel on Cu (001), new film modes are identified experimentally and correspond to vibrational motion localized primarily in the film. Measurements for epitaxial films of cobalt on a Cu (001) substrate exhibit substantial flattening of the Rayleigh phonon dispersion, suggestive of surface stress in the films.

Research Organization:
Indiana Univ., Bloomington (USA)
DOE Contract Number:
FG02-84ER45147
OSTI ID:
6099429
Report Number(s):
DOE/ER/45147-4; ON: DE89013964
Country of Publication:
United States
Language:
English