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U.S. Department of Energy
Office of Scientific and Technical Information

NMR shift reagents

Book ·
OSTI ID:6087763
This practical guide to current and potential users of lanthanide shift reagents (LSR) describes the selection of a LSR and the experimental techniques necessary to prepare and properly employ the various types of LSR. It gives a thorough review of previous literature reports in which lanthanide tris chelates and binuclear lanthanide-silver shift reagents were used in organic solvents to study achiral and chiral substrates, with particular focus on the sterochemical and conformational information obtained through use of LSR. It describes LSR suitable for use in aqueous solutions as well as computer fitting of lanthanide shift data through the dipolar shift equation. Other valuable information includes over 800 structures and 1500 references.
OSTI ID:
6087763
Country of Publication:
United States
Language:
English