Crystal and molecular structure of bis(diisopropylphenylphosphine)hexahydridoosmium, (OsH/sub 6/(PC/sub 12/H/sub 19/)/sub 2/): single-crystal neutron diffraction study at 20 K
Journal Article
·
· Inorg. Chem.; (United States)
The crystal and molecular structure of the hexahydridoosmium complex (OsH/sub 6/(PC/sub 12/H/sub 19/)/sub 2/), determined from a low-temperature X-ray diffraction analysis, has been refined on the basis of neutron diffraction data obtained at 20 K. The dodecahedral ML/sub 2/H/sub 6/ core has approximate mm symmetry with the phosphines in equivalent B (five-neighbor) sites and a P-Os-P angle of 155.2 (1)/sup 0/. The Os-H distances range from 1.637 (4) to 1.668 (4) A, with a mean value of 1.649 (5) A. Crystal data at 20.0 (5) K: a = 17.016 (3) A, b = 13.762 (3) A, c = 10.857 (3) A, ..beta.. = 98.91 (2)/sup 0/, V = 2512 (1) A/sup 3/, monoclinic, P2/sub 1//n, Z = 4, M/sub r/ 584.8. 29 references, 2 figures, 3 tables.
- Research Organization:
- Univ. of Bristol, England
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6087337
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 26:18; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
MOLECULAR STRUCTURE
NEUTRON DIFFRACTION
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPOUNDS
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SCATTERING
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
AROMATICS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
MOLECULAR STRUCTURE
NEUTRON DIFFRACTION
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPOUNDS
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SCATTERING
TRANSITION ELEMENT COMPOUNDS