Limiting law for distinct diffusion coefficients in ionic solutions

Journal Article · Fri May 01 04:00:00 EDT 1987 · J. Solution Chem.; (United States)

DOI:https://doi.org/10.1007/BF00647182· OSTI ID:6086868

Zhong, E C; Friedman, H L

The limiting laws for the distinct diffusion coefficient and the corresponding Onsager phenomenological coefficient are obtained from the cluster theory of electrolyte conductance. Results are given for single electrolytes and common-ion mixtures with unrestricted charges and friction coefficients in both cases.

• Research Organization: State Univ. of New York, Stony Brook
• OSTI ID: 6086868
• Journal Information: J. Solution Chem.; (United States), Journal Name: J. Solution Chem.; (United States) Vol. 16:5; ISSN JSLCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400400 -- Electrochemistry
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
BROWNIAN MOVEMENT
CHARGED-PARTICLE TRANSPORT THEORY
CHLORIDES
CHLORINE COMPOUNDS
CORRELATION FUNCTIONS
COULOMB FIELD
DEBYE LENGTH
DIFFUSION
DIMENSIONS
DISTANCE
ELECTRIC CONDUCTIVITY
ELECTRIC FIELDS
ELECTRICAL PROPERTIES
ELECTROLYTES
ELECTROPHORESIS
FLUID MECHANICS
FRICTION FACTOR
FUNCTIONS
HALIDES
HALOGEN COMPOUNDS
HYDRODYNAMICS
INTERACTION RANGE
INTERACTIONS
ION MOBILITY
IONIC CONDUCTIVITY
LENGTH
LIMITING VALUES
MAGNESIUM CHLORIDES
MAGNESIUM COMPOUNDS
MATHEMATICAL MODELS
MECHANICS
MOBILITY
ONSAGER RELATIONS
PARTICLE INTERACTIONS
PARTICLE MOBILITY
PARTICLE MODELS
PHYSICAL PROPERTIES
SODIUM CHLORIDES
SODIUM COMPOUNDS
STATISTICAL MECHANICS
THERMODYNAMICS
TRANSPORT THEORY
VAN HOVE MODEL