Stability constants and thermodynamic data for complexes of 12-crown-4 with alkali metal and alkaline-earth cations in methanol solutions
Journal Article
·
· J. Solution Chem.; (United States)
The formation of 1:1- and 2:1-complexes of the crown ether 12C4 with mono- and bivalent cations was studied in methanol solutions by calorimetric, potentiometric and conductometric titrations. It is shown that not all donor atoms of the ligand 12C4 take part in complex formation. The accuracy of the three experimental methods are checked by comparing the results for the complexation of alkali ions with crown ether 18C6.
- Research Organization:
- Universitaet-GH Siegen, West Germany
- OSTI ID:
- 6086816
- Journal Information:
- J. Solution Chem.; (United States), Journal Name: J. Solution Chem.; (United States) Vol. 16:3; ISSN JSLCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPLEXES
ALKALINE EARTH METAL COMPOUNDS
BARIUM BROMIDES
BARIUM COMPOUNDS
BARIUM PERCHLORATES
BORIDES
BORON COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM NITRATES
CALORIMETRY
CESIUM BROMIDES
CESIUM COMPOUNDS
CESIUM FLUORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
ENERGY
FLUORIDES
FLUORINE COMPOUNDS
GLYCOLS
HALIDES
HALOGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC PHOSPHORS
IODIDES
IODINE COMPOUNDS
LITHIUM COMPOUNDS
METHANOL
NITRATES
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PERCHLORATES
PHOSPHORS
PHYSICAL PROPERTIES
POLYETHYLENE GLYCOLS
POLYMERS
POTASSIUM BROMIDES
POTASSIUM COMPOUNDS
POTASSIUM IODIDES
POTENTIOMETRY
RUBIDIUM BROMIDES
RUBIDIUM COMPOUNDS
RUBIDIUM NITRATES
SILVER COMPOUNDS
SILVER NITRATES
SODIUM BORIDES
SODIUM COMPOUNDS
SODIUM NITRATES
SOLVENT PROPERTIES
STABILITY
STRONTIUM COMPOUNDS
STRONTIUM NITRATES
THERMODYNAMIC PROPERTIES
TITRATION
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPLEXES
ALKALINE EARTH METAL COMPOUNDS
BARIUM BROMIDES
BARIUM COMPOUNDS
BARIUM PERCHLORATES
BORIDES
BORON COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM NITRATES
CALORIMETRY
CESIUM BROMIDES
CESIUM COMPOUNDS
CESIUM FLUORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
ENERGY
FLUORIDES
FLUORINE COMPOUNDS
GLYCOLS
HALIDES
HALOGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC PHOSPHORS
IODIDES
IODINE COMPOUNDS
LITHIUM COMPOUNDS
METHANOL
NITRATES
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PERCHLORATES
PHOSPHORS
PHYSICAL PROPERTIES
POLYETHYLENE GLYCOLS
POLYMERS
POTASSIUM BROMIDES
POTASSIUM COMPOUNDS
POTASSIUM IODIDES
POTENTIOMETRY
RUBIDIUM BROMIDES
RUBIDIUM COMPOUNDS
RUBIDIUM NITRATES
SILVER COMPOUNDS
SILVER NITRATES
SODIUM BORIDES
SODIUM COMPOUNDS
SODIUM NITRATES
SOLVENT PROPERTIES
STABILITY
STRONTIUM COMPOUNDS
STRONTIUM NITRATES
THERMODYNAMIC PROPERTIES
TITRATION
TRANSITION ELEMENT COMPOUNDS