Photoionization dynamics of excited molecular states: D2 C ¹Πu
Journal Article
·
· Journal of Chemical Physics
- Argonne National Lab. (ANL), Argonne, IL (United States)
The three photon resonant, four photon ionization spectra of D₂ via the C ¹Πu, v'=0–4 levels are reported. The photoelectron spectra for all five bands and the photoelectron angular distribution via the C ¹Πu, v'=0--3←X ¹Σ⁺g, v''=0, Q(3) transitions are also reported. The photoelectron spectra are compared with theoretical Franck--Condon factors determined using accurate potential curves for the D₂ C ¹πu and D⁺₂ X ²Σ⁺g states. As in the case of H₂, the photoelectron spectra display non-Franck–Condon behavior, and the photoelectron angular distributions exhibit strong v⁺ dependences. The relation of the present results to earlier results on H₂ is discussed.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE; Office of Health and Environmental Research (OHER); Office of Naval Research (ONR)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6085315
- Journal Information:
- Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 8 Vol. 87; ISSN JCPSA6; ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
Similar Records
Photoionization dynamics of excited molecular states. Photoelectron angular distributions and rotational and vibrational branching ratios for H2 C ¹Πu, v=0–4
Photoionization of excited molecular states using multiphoton excitation techniques
Photoelectron studies of resonantly enhanced multiphoton ionization of H2 via the B' 1Σ+u and D 1Πu states
Journal Article
·
Tue Dec 31 23:00:00 EST 1985
· Journal of Chemical Physics
·
OSTI ID:5086257
Photoionization of excited molecular states using multiphoton excitation techniques
Conference
·
Sat Dec 31 23:00:00 EST 1983
·
OSTI ID:5211610
Photoelectron studies of resonantly enhanced multiphoton ionization of H2 via the B' 1Σ+u and D 1Πu states
Journal Article
·
Wed Dec 31 23:00:00 EST 1986
· Journal of Chemical Physics
·
OSTI ID:6925626
Related Subjects
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANGULAR DISTRIBUTION
DEUTERIUM
DISTRIBUTION
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ENERGY LEVELS
EXCITED STATES
FRANCK-CONDON PRINCIPLE
HYDROGEN ISOTOPES
IONIZATION
ISOTOPES
LIGHT NUCLEI
MULTI-PHOTON PROCESSES
NUCLEI
ODD-ODD NUCLEI
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
SPECTROSCOPY
STABLE ISOTOPES
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANGULAR DISTRIBUTION
DEUTERIUM
DISTRIBUTION
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ENERGY LEVELS
EXCITED STATES
FRANCK-CONDON PRINCIPLE
HYDROGEN ISOTOPES
IONIZATION
ISOTOPES
LIGHT NUCLEI
MULTI-PHOTON PROCESSES
NUCLEI
ODD-ODD NUCLEI
PHOTOELECTRON SPECTROSCOPY
PHOTOIONIZATION
SPECTROSCOPY
STABLE ISOTOPES