Synthesis, structure, electrochemistry, and photophysics of methyl-substituted phenylpyridine ortho-metalated iridium(III) complexes
Journal Article
·
· Inorg. Chem.; (United States)
Synthetic, structural, photophysical, and electrochemical characterizations of ortho-metalated (Ir(NC)/sub 2/Cl)/sub 2/ dimeric and (Ir(NC)/sub 2/NN)Cl monomeric complexes, where NC = 2(p-tolyl)pyridine (ptpy) or 3-methyl-2-phenylpyridine (mppy) and NN = 2,2'-bipyridine (bpy) are described. Structural characterizations by /sup 1/H and /sup 13/C nuclear magnetic resonance (NMR) indicate the presence of symmetry elements in these complexes. The ultraviolet-visible absorption properties of these complexes are reported. The results of voltametric measurements of these complexes are included. 55 references, 10 figures, 6 tables.
- Research Organization:
- Univ. of California, Santa Barbara (USA)
- DOE Contract Number:
- AT03-76ER70277
- OSTI ID:
- 6084873
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:20; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ARYL RADICALS
AZINES
BARYONS
BIPYRIDINES
CARBON 13
CARBON ISOTOPES
COMPLEXES
DATA
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
IRIDIUM COMPLEXES
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROTONS
PYRIDINES
RADICALS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TOLYL RADICALS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ARYL RADICALS
AZINES
BARYONS
BIPYRIDINES
CARBON 13
CARBON ISOTOPES
COMPLEXES
DATA
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
IRIDIUM COMPLEXES
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROTONS
PYRIDINES
RADICALS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TOLYL RADICALS
TRANSITION ELEMENT COMPLEXES