Polyoxoanion mediated methane activation and functionalization: Molecular design of new homogeneous and new solid state/heterogeneous catalysts
The overall goal of our DOE-funded research is to develop a chemical paradigm for polyoxoanion-supported transition-metal catalysis, with an emphasis on small molecule (H{sub 2}, O{sub 2}, CH{sub 4}) catalytic activation and functionalization (CH{sub 4}, RH). Sub-goals or sub-projects include solution (i.e. homogeneous) catalysis studies, and then the preparation and study where warranted of a new class of novel, polyoxoanion-based solid-state (heterogeneous) catalysts. Kinetic and mechanistic studies are an integral part of this work. The sub-projects are: catalytic and mechanistic studies of H{sub 2}, O{sub 2}, CH{sub 4} and other alkane activations, O{sub 2} activation and catalytic oxidations using (1,5-COD)Ir{center dot}P{sub 2}W{sub 15}Nb{sub 3}O{sub 62}{sup 8{minus}}, and alkane, olefin and arene hydroxylations by P{sub 2}W{sub 17}O{sub 61}MnO{sub 61}{sup 7{minus}} and PhIO.
- Research Organization:
- Oregon Univ., Eugene, OR (USA). Dept. of Chemistry
- Sponsoring Organization:
- DOE/ER
- DOE Contract Number:
- FG06-89ER13998
- OSTI ID:
- 6082064
- Report Number(s):
- DOE/ER/13998-2; ON: DE91005564
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ALKANES
ALKENES
CATALYSIS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
DOCUMENT TYPES
HYDROCARBONS
HYDROXYLATION
IRIDIUM COMPLEXES
NIOBIUM COMPOUNDS
NIOBIUM OXIDES
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS OXIDES
PROGRESS REPORT
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN OXIDES