Synthesis and reactivity of ruthenium hydride complexes of chelating triphosphines. 3. Synthesis and characterization of new ruthenium hydride complexes containing C sub 6 H sub 5 P(CH sub 2 CH sub 2 CH sub 2 P(c-C sub 6 H sub 11 ) sub 2 ) sub 2 (Cyttp)

Journal Article · Fri Feb 01 04:00:00 EST 1991 · Inorganic Chemistry; (United States)

DOI:https://doi.org/10.1021/ic00003a010· OSTI ID:6079137

Jia, Guochen; Meek, D W; Gallucci, J C

The hydride complex RuH(BH{sub 4})(Cyttp) was produced from the reaction of RuCl{sub 2}(Cyttp) with excess NaBH{sub 4}. A series of six-coordinate RuHCl(L)(Cyttp) complexes (L = CO, P(OMe){sub 3}, CH{sub 3}CN) were synthesized from RuHCl(Cyttp), which was prepared from the reaction of RuCl{sub 2}(Cyttp) and excess lithium hydride in THF. Ruthenium dihydride complexes RuH{sub 2}(L)(Cyttp) (L = CO, N{sub 2}, CNCH{sub 2}C{sub 6}H{sub 5}, P(OMe){sub 3}, and P(OPh){sub 3}) were synthesized from RuH{sub 2}(H{sub 2})(Cyttp), which was prepared from the reaction of RuCl{sub 2}(Cyttp) with NaH in THF under a H{sub 2} atmosphere. The new compounds were characterized by microanalyses and infrared and {sup 1}H and {sup 31}P NMR spectroscopy. The crystal structure of RuII{sub 2} (N{sub 2})(Cyttp) was determined and is reported here.

• OSTI ID: 6079137
• Journal Information: Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 30:3; ISSN 0020-1669; ISSN INOCA
• Country of Publication: United States
• Language: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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ALKENES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
CRYSTAL STRUCTURE
DATA
EXPERIMENTAL DATA
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGENATION
INFORMATION
ISOMERIZATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
POLYMERIZATION
RUTHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES