Crystal structures of [Gd[sub 6](O)(OH)[sub 8](NO[sub 3])[sub 6](OH[sub 2])[sub 12]]-[NO[sub 3]][sub 2][center dot]2H[sub 2]O and [NH[sub 4]][sub 2][Yb[sub 6](O)(OH)[sub 8](NO[sub 3])[sub 7](OH[sub 2])[sub 10]]-[NO[sub 3]][sub 3][center dot]H[sub 2]O
Journal Article
·
· Journal of Crystallographic and Spectroscopic Research; (United States)
- Northern Illinois Univ., DeKalb (United States)
Two similar oxy-hydroxy-nitrate lanthanide(III) complexes were unexpectedly isolated from the reaction of Ln(NO[sub 3])[sub 3][center dot]5H[sub 2]O with tripropylene glycol in 3:1 CH[sub 3]CN:CH[sub 3]OH. The crystal structures of these two compounds revealed identical [Ln[sub 6](O)(OH)[sub 8]][sup 8+] central cores and are reported here.
- OSTI ID:
- 6078830
- Journal Information:
- Journal of Crystallographic and Spectroscopic Research; (United States), Vol. 23:6; ISSN 0277-8068
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6078830
+1 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
GADOLINIUM COMPLEXES
CRYSTAL STRUCTURE
YTTERBIUM COMPLEXES
GADOLINIUM HYDROXIDES
GADOLINIUM NITRATES
GADOLINIUM OXIDES
HYDRATES
MOLECULAR STRUCTURE
NITRATES
X-RAY DIFFRACTION
YTTERBIUM HYDROXIDES
YTTERBIUM OXIDES
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
GADOLINIUM COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXIDES
NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
SCATTERING
YTTERBIUM COMPOUNDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
GADOLINIUM COMPLEXES
CRYSTAL STRUCTURE
YTTERBIUM COMPLEXES
GADOLINIUM HYDROXIDES
GADOLINIUM NITRATES
GADOLINIUM OXIDES
HYDRATES
MOLECULAR STRUCTURE
NITRATES
X-RAY DIFFRACTION
YTTERBIUM HYDROXIDES
YTTERBIUM OXIDES
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
GADOLINIUM COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXIDES
NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
SCATTERING
YTTERBIUM COMPOUNDS
400201* - Chemical & Physicochemical Properties