Froth flotation of oil-bearing metal sulfide wastes
- Idaho National Engineering Lab., Idaho Falls, ID (United States)
- Advanced Processing Technologies, Inc., Salt Lake City, UT (United States)
An industrial wastewater, including plating wastes, is treated with sodium sulfide and ferrous sulfate to form a sulfide-oxide precipitate containing chromium and other toxic metals. Hydrocarbons, in the water, coat the sulfide-oxide particles, impeding metal recovery. Froth flotation, without reagent addition, was found to recover 93.9% of the solids from the sludge with simultaneous rejection of 89% of the water. Methyl isobutyl carbinol (MIBC) improved recovery and potassium amyl xanthate improved both recovery and grade. The process design has wastewater feed (without MIBC) to the rougher circuit. The rougher concentrate is conditioned with MIBC and fed to a cleaner circuit to achieve a high grade concentrate. About 95% of the water is recirculated to the waste treatment plant. 3 refs., 3 figs., 4 tabs.
- Research Organization:
- EG and G Idaho, Inc., Idaho Falls, ID (United States)
- Sponsoring Organization:
- DOD; Department of Defense, Washington, DC (United States)
- DOE Contract Number:
- AC07-76ID01570
- OSTI ID:
- 6071556
- Report Number(s):
- EGG-M-91315; CONF-920305--2; ON: DE92003285
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
320305* -- Energy Conservation
Consumption
& Utilization-- Industrial & Agricultural Processes-- Industrial Waste Management
ADDITIVES
ALKALI METAL COMPOUNDS
ANTIGENS
CHALCOGENIDES
CHROMIUM
DEPOSITION
ELEMENTS
FLOTATION
HYDROCARBONS
HYDROGEN COMPOUNDS
INDUSTRIAL WASTES
IRON COMPOUNDS
IRON SULFATES
LIQUID WASTES
MANAGEMENT
MATERIALS
METALS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATING
PRECIPITATION
PROCESSING
REMOVAL
SEPARATION PROCESSES
SLUDGES
SODIUM COMPOUNDS
SODIUM SULFIDES
SULFATES
SULFIDES
SULFUR COMPOUNDS
SURFACE COATING
TOXIC MATERIALS
TOXINS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
WASTE MANAGEMENT
WASTE PROCESSING
WASTE WATER
WASTES
WATER
WATER TREATMENT
XANTHATES