Free-energy dependence of long-range electron transfer from neutral donors to cationic acceptors as studied by the pulse radiolysis method. [Electron beams - 2. 7 MeV]

Journal Article · Thu Oct 15 00:00:00 EDT 1981 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j150621a008· OSTI ID:6071125

Kira, A

Kinetic measurement by the pulse radiolysis method was carried out for electron transfers from neutral donors of amines and aromatic hydrocarbons to radiation-induced cationic acceptors, trapped holes and solute cations, in sec-butyl chloride glasses at 77 K. The decay of the cationic acceptor was monitored over 3 ..mu..s-8 s. Franck-Condon factors calculated from the decay curves increase with -..delta..G, the free-energy difference in a donor-acceptor system, in the region of -..delta..G < 0.8 eV and then become almost constant up to -..delta..G approx. = 3 eV.

• Research Organization: Inst. of Physical and Chemical Research, Saitama, Japan
• OSTI ID: 6071125
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:21; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
AMINES
AROMATICS
BEAMS
BENZENE
BIPHENYL
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATED AROMATIC HYDROCARBONS
CONDENSED AROMATICS
DATA
DECAY
DECOMPOSITION
ELECTRON BEAMS
ELECTRON TRANSFER
ENERGY RANGE
EXPERIMENTAL DATA
FLUORENE
GLASS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
IRRADIATION
LEPTON BEAMS
LOW TEMPERATURE
MEV RANGE
MEV RANGE 01-10
NAPHTHALENE
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PARTICLE BEAMS
PHENANTHRENE
PULSED IRRADIATION
PYRENE
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
TIME DEPENDENCE
TOLUENE