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Fate of toxic organic compounds in activated sludge and integrated activated sludge/carbon treatment systems. Volumes I and II

Thesis/Dissertation ·
OSTI ID:6069154

Results from steady-state bioreactor studies indicated that 70 to 90% of the influent fluxes of benzene, toluene, ethylbenzene, o-xylene, chlorobenzene, and nitrobenzene and approximately 35% of the influent flux of 1,2-dichlorobenzene were biodegraded by acclimated activated sludges. Biodegradation effected approximately equal percent reductions in effluent and off-gas concentrations of the volatile, biodegradable compounds. Acclimation periods for all biodegradable compounds ranged from 14 to 21 days. Lindane and 1,2,4-trichlorobenzene were found to be nonbiodegradable in the experimental system. Results from steady-state bioreactor studies showed that the addition of less than 100 mg/l powdered activated carbon did not enhance the removal of the biodegradable compounds benzene, toluene, ethylbenzene, o-xylene, chlorobenzene, and nitrobenzene. Significantly improved removals of the poorly and non-biodegradable compounds, 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, and lindane, occurred at influent powdered carbon concentrations in the 12.5 to 25 mg/l range. Influent PAC concentrations of 100 mg/l effected overall removals greater than 90%. The addition of powdered activated carbon not only reduced effluent concentration, but also reduced amounts of the volatile compounds stripped to the atmosphere. PAC-bioreactor studies demonstrated that the influent PAC concentration rather than the mixed liquor PAC concentration controlled the amounts of the compounds removed during steady-state operating periods.

Research Organization:
Michigan Univ., Ann Arbor (USA)
OSTI ID:
6069154
Country of Publication:
United States
Language:
English