Electron accumulation in nanostructured TiO[sub 2] (anatase) electrodes

Journal Article · Thu Sep 16 04:00:00 EDT 1999 · Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical

DOI:https://doi.org/10.1021/jp983040m· OSTI ID:6067426

Boschloo, G; Fitzmaurice, D ^[1]

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1. Univ. Coll. Dublin, Belfield (Ireland). Dept. of Chemistry

If both the technological and commercial potential of nanostructured metal oxide electrodes are to be fully realized, it will be important to understand the effects of electrolyte composition on the extent of electron accumulation and the nature of charge compensation at different applied potentials. Having studied the potential dependent optical absorption spectroscopy of nanostructured TiO[sub 2] (anatase) electrodes in different electrolytes, the authors concluded that the extent and nature of charge accumulation and compensation depends on whether the potential applied corresponds to weak (<40 mC cm[sup [minus]2]) or strong (>40 mC cm[sup [minus]2]) accumulation conditions, on whether the electrolyte is prepared using a protic or aprotic solvent, and on whether the ions present in the electrolyte are capable of being intercalated or not.

• OSTI ID: 6067426
• Journal Information: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical, Journal Name: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical Vol. 103:37; ISSN 1089-5647; ISSN JPCBFK
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360204* -- Ceramics
Cermets
&amp; Refractories-- Physical Properties
ABSORPTION SPECTROSCOPY
CHALCOGENIDES
CHARGE CARRIERS
CRYSTALS
ELECTRODES
ELECTROLYTES
MATERIALS
OXIDES
OXYGEN COMPOUNDS
POROUS MATERIALS
SOLVENTS
SPECTROSCOPY
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS