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Effect of soil type on the extractability of /sup 237/Np, /sup 239/Pu, /sup 241/Am, and /sup 244/Cm as a function of pH

Journal Article · · Soil Sci.; (United States)
OSTI ID:6060034

Using an equilibrium batch technique, we determined the extractability of /sup 237/Np, /sup 239/Pu, /sup 241/Am, and /sup 244/Cm from widely different kinds of soils as a function of pH. Hydrochloric acid or NaOH was used to adjust the pH. The sorption and extractability of the transuranics studied varied considerably with pH and the kind of soil. A general pattern of extractability, common to all the transuranics studied, was exhibited to a varying degree by each mineral soil, except the calcareous soil. Typically, the extractability was relatively high under strongly acidic conditions, particularly below pH 2. Then, as the pH increased, there was a zone of rapid decrease, which was followed by a peak with increasing pH and then a decline. The organic soil used differed from this general pattern in that it showed a progressive increase of extractability in the alkaline pH range instead of peaking and declining.

Research Organization:
Univ. of California, Los Angeles
OSTI ID:
6060034
Journal Information:
Soil Sci.; (United States), Journal Name: Soil Sci.; (United States) Vol. 132:1; ISSN SOSCA
Country of Publication:
United States
Language:
English

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