Rates and temperature dependences of the reaction of OH with isoprene, its oxidation products, and selected terpenes

Journal Article · Wed Dec 01 04:00:00 EST 1982 · Environ. Sci. Technol.; (United States)

DOI:https://doi.org/10.1021/es00106a004· OSTI ID:6056932

Kleindienst, T E; Harris, G W; Pitts, Jr, J N

Absolute rate constants determined by using the flash photolysis-resonance fluorescence technique are reported for the reactions of hydroxyl radicals with isoprene, ..cap alpha.., and ..beta..-pinene, methyl vinyl ketone, and methacrolein in the temperature range 297-424 K, and with methylglyoxal at 297 K. These results contribute to a more quantitative understanding of the tropospheric fate of gas-phase biomass-related organics and serve as input to models of the chemistry of the natural troposphere.

• Research Organization: Univ. of California, Riverside
• OSTI ID: 6056932
• Journal Information: Environ. Sci. Technol.; (United States), Journal Name: Environ. Sci. Technol.; (United States) Vol. 16:12; ISSN ESTHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DIENES
FLUORESCENCE
HYDROCARBONS
HYDROXYL RADICALS
ISOPRENE
KINETICS
LUMINESCENCE
ORGANIC COMPOUNDS
OXIDATION
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
POLLUTION
POLYENES
RADICALS
REACTION KINETICS
TEMPERATURE DEPENDENCE
TERPENES