Properties of supported metal catalysts. Final report

Technical Report · Sun Jan 01 04:00:00 EST 1984

OSTI ID:6056308

Butt, J B; Burwell, Jr, R L; Cohen, J B

We have investigated all catalysts by WAXS as a function of pretreatment and some by SAXS. Studies of EXAFS and some studies of WAXS have been performed at CHESS. The hydrogenolysis of methylcyclopropane and the isotopic exchange between cyclopentane and deuterium has been studied on all catalysts and the hydrogenation of propylene and the isotopic exchange between deuterium and neohexane have been studied on Pt/SiO/sub 2/ and Pd/SiO/sub 2/. We have made detailed studies of the reaction of oxygen with reduced catalysts and of hydrogen with oxidized catalysts.

• Research Organization: Northwestern Univ., Evanston, IL (USA). Ipatieff High Pressure and Catalytic Lab.
• DOE Contract Number: AC02-77ER04254
• OSTI ID: 6056308
• Report Number(s): DOE/ER/04254-6; ON: DE85003927
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360104* -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400303 -- Organic Chemistry-- Isotope Exchange & Isotope Separation-- (-1987)
ALKANES
ALKENES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AROMATICS
BENZENE
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CYCLOALKANES
DEUTERIUM
ELEMENTS
HYDROCARBONS
HYDROGEN ISOTOPES
HYDROGENATION
ISOTOPES
ISOTOPIC EXCHANGE
LIGHT NUCLEI
MECHANICAL STRUCTURES
METALS
MINERALS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
OXIDE MINERALS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
PALLADIUM
PLATINUM
PLATINUM METALS
PROPYLENE
RHODIUM
SILICA
SILICON COMPOUNDS
SILICON OXIDES
STABLE ISOTOPES
SUPPORTS
TRANSITION ELEMENTS