Reaction of SO2 with transition-metal hydrides. Synthesis and structure of ( -H)2Os3(CO)10( -SO2)
Journal Article
·
· Organometallics; (United States)
The reaction of SO2 with the unsaturated cluster ( -H)2Os3(CO)10 yields the adduct ( -H)2Os3(CO)10( -SO2). The crystal structure of the adduct was determined and is reported. The molecular structure of the adduct was also determined and is closely related to that of the methylene complex.
- Research Organization:
- Los Alamos National Lab., NM
- OSTI ID:
- 6052750
- Journal Information:
- Organometallics; (United States), Vol. 3:9
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydrogenation of small molecules by transition metal cluster hydrides. Reaction of H/sub 2/Os/sub 3/(CO)/sub 10/ with carbon disulfide
Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction study of the crystal and molecular structure of (. mu. -H)/sub 2/Os/sub 3/(CO)/sub 10/(. mu. -CH/sub 2/)
Cluster synthesis. 40. New high-nuclearity platinum-ruthenium carbonyl cluster complexes. Synthesis and structural characterizations of Ru[sub 8]Pt[sub 2](CO)[sub 23]([mu][sub 3]-H)[sub 2], Ru[sub 7]Pt[sub 3](CO)[sub 22]([mu][sub 3]-H)[sub 2], and Ru[sub 8]Pt[sub 2](CO)[sub 21]([mu][sub 3]-[eta][sup 2]-CO)[sub 2](dppe)([mu]-H)[sub 2] with a new type of triply bridging CO ligand and the new layered cluster complex Ru[sub 6]Pt[sub 3](CO)[sub 21]([mu]-CO)([mu][sub 3]-H)[sub 2]
Journal Article
·
Wed Feb 28 00:00:00 EST 1979
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6052750
Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction study of the crystal and molecular structure of (. mu. -H)/sub 2/Os/sub 3/(CO)/sub 10/(. mu. -CH/sub 2/)
Journal Article
·
Thu Feb 01 00:00:00 EST 1979
· Inorg. Chem.; (United States)
·
OSTI ID:6052750
+2 more
Cluster synthesis. 40. New high-nuclearity platinum-ruthenium carbonyl cluster complexes. Synthesis and structural characterizations of Ru[sub 8]Pt[sub 2](CO)[sub 23]([mu][sub 3]-H)[sub 2], Ru[sub 7]Pt[sub 3](CO)[sub 22]([mu][sub 3]-H)[sub 2], and Ru[sub 8]Pt[sub 2](CO)[sub 21]([mu][sub 3]-[eta][sup 2]-CO)[sub 2](dppe)([mu]-H)[sub 2] with a new type of triply bridging CO ligand and the new layered cluster complex Ru[sub 6]Pt[sub 3](CO)[sub 21]([mu]-CO)([mu][sub 3]-H)[sub 2]
Journal Article
·
Tue Dec 01 00:00:00 EST 1992
· Organometallics; (United States)
·
OSTI ID:6052750
+1 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
MOLECULAR STRUCTURE
COMPLEXES
OSMIUM COMPOUNDS
SULFUR DIOXIDE
EXPERIMENTAL DATA
CHALCOGENIDES
DATA
INFORMATION
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
SULFUR COMPOUNDS
SULFUR OXIDES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
MOLECULAR STRUCTURE
COMPLEXES
OSMIUM COMPOUNDS
SULFUR DIOXIDE
EXPERIMENTAL DATA
CHALCOGENIDES
DATA
INFORMATION
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
SULFUR COMPOUNDS
SULFUR OXIDES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)