Reactions of the Mo[double bond]S bond in the [(Cp)Mo(O)([mu]-S)[sub 2]Mo(O)(S)][sup [minus]] complex with SO[sub 2]. An [sup 1]H NMR study and the synthesis and structural characterization of [(Cp)Mo(O)([mu]-S)[sub 2]Mo(O)(L)][sup [minus]] complexes containing SO[sub 2]-derived sulfite, thiosulfate, and sulfate bidentate chelating ligands
Journal Article
·
· Inorganic Chemistry; (United States)
- Univ. of Michigan, Ann Arbor (United States)
The reactions of the Mo[double bond]S unit in the [(Cp)Mo(O)([mu]-S)[sub 2]Mo(O)(S)][sup [minus]] complex with SO[sub 2] at various temperatures give various products of the type [(Cp)Mo(O)([mu]-S)[sub 2]Mo(O)(L)][sup [minus]] (L = SO[sub 3][sup 2[minus]], S[sub 2]O[sub 3][sup 2[minus]], and SO[sub 4][sup 2[minus]]). A [sup 1]H-NMR study of these reactions indicates that the final products isolated and structurally characterized are derivatives of the unstable [(Cp)Mo(O)([mu]-S)[sub 2]Mo(O)(S[sub 2]O[sub 2])][sup [minus]] complex that forms initially by SO[sub 2] addition to the Mo[double bond]S unit and undergoes further reactions with SO[sub 2]. 12 refs., 2 figs.
- OSTI ID:
- 6046557
- Journal Information:
- Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 32:10; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHALCOGENIDES
CHELATES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
MOLYBDENUM SULFIDES
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
RESONANCE
SULFATES
SULFIDES
SULFITES
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
SYNTHESIS
THIOSULFATES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
CHALCOGENIDES
CHELATES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
MOLYBDENUM SULFIDES
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
RESONANCE
SULFATES
SULFIDES
SULFITES
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
SYNTHESIS
THIOSULFATES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS