Efficient synthesis of substituted uranocenes

Journal Article · Tue May 01 04:00:00 EDT 1979 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic50195a027· OSTI ID:6040734

Miller, J T; DeKock, C W

Dilithium n-butylcyclooctatetraenide is prepared by reaction of 2 equiv of n-butyllithium with 1 equiv of cyclooctatetraene in diethyl ether at 25/sup 0/C. Treatment of this solution with 0.5 equiv of UCl/sub 4/ dissolved in tetrahydrofuran followed by Soxhlet extraction with hexane resulted in a 50% yield of 1,1'-di-n-butyluranocene based on cyclooctatetraene. Treatment of 1,1'-di-n-butyluranocene with nitrobenzene resulted in a 51% yield of azobenzene based on cyclooctatetraene.

• Research Organization: Oregon State Univ., Corvallis
• OSTI ID: 6040734
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 18:5; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPOUNDS
ALKALI METAL COMPOUNDS
AROMATICS
AZO COMPOUNDS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CONDENSED AROMATICS
HALIDES
HALOGEN COMPOUNDS
LITHIUM COMPOUNDS
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
SYNTHESIS
URANIUM CHLORIDES
URANIUM COMPOUNDS