In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic lattice is well established for FeOCl, and in the present case affords a novel class of conductive polymer-inorganic hybrid materials. The reaction of FeOCl with excess neat pyrrole (60/sup 0/C) yields a material analyzing as (Ppy)/sub 0.34/FeOCl. X-ray diffraction measurements reveal high crystallinity and an increase in FeOCl interlayer (b-axis) spacing from 7.980 to 13.210 A.
- Research Organization:
- Northwestern Univ., Evanston, IL
- OSTI ID:
- 6036652
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 109:12; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360603 -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AZOLES
CHEMICAL PREPARATION
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
FOURIER TRANSFORM SPECTROMETERS
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
INCLUSIONS
INFORMATION
INFRARED SPECTRA
IRON COMPOUNDS
MATERIALS
MEASURING INSTRUMENTS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SEMICONDUCTORS
OXYCHLORIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
POLYMERS
PYRROLES
SCATTERING
SEMICONDUCTOR MATERIALS
SPECTRA
SPECTROMETERS
SURFACE PROPERTIES
SYNTHESIS
THERMOELECTRIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
VAN DER WAALS FORCES
X-RAY DIFFRACTION
360603 -- Materials-- Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AZOLES
CHEMICAL PREPARATION
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
FOURIER TRANSFORM SPECTROMETERS
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
INCLUSIONS
INFORMATION
INFRARED SPECTRA
IRON COMPOUNDS
MATERIALS
MEASURING INSTRUMENTS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SEMICONDUCTORS
OXYCHLORIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
POLYMERS
PYRROLES
SCATTERING
SEMICONDUCTOR MATERIALS
SPECTRA
SPECTROMETERS
SURFACE PROPERTIES
SYNTHESIS
THERMOELECTRIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
VAN DER WAALS FORCES
X-RAY DIFFRACTION