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Synthesis and structure of 4,4-dichloro-2-methyl-1,3-butadienes (in Russian)

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6036467
; ;

The reaction of 4,4,4-trichloro-2-methyl-2-butenal with zinc and aliphatic acid chlorides has been studied. In a medium of ether and ethyl acetate the reaction gives 4,4-dichloro-2-methyl-1-acyloxy-1,3-butadienes in the form of a mixture of E and Z isomers. The IR and PMR spectra of the final reaction products have been studied, and the conditions for the isolation of the pure E isomers have been found.

OSTI ID:
6036467
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:7; ISSN JOCYA
Country of Publication:
United States
Language:
Russian

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETIC ACID ESTERS
ACTIVATION ENERGY
ALDEHYDES
CARBOXYLIC ACID ESTERS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
COUPLING
COUPLING CONSTANTS
DIENES
ENERGY
ESTERS
ETHERS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
POLYENES
SPECTRA
SYNTHESIS
YIELDS
ZINC CHLORIDES
ZINC COMPOUNDS
ZINC HALIDES