Migrations of the phenylseleno group along the perimeter of the cyclopentadiene ring

Journal Article · Thu Nov 20 04:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6036320

Mikhailov, I E; Minkin, V I; Klenkin, A A; Okekhnovich, L P

The reaction of the lithium salt of pentamethylcyclopentadiene with benzene-selenyl chloride leads to the formation of 5-phenylseleno-1,2,3,4,5-pentamethyl-cyclopentadiene and also decamethylbi(cyclopenta-2,4-dienyl) and diphenyl diselenide. The /sup 1/H NMR spectra were obtained on a Tesla BS-487C spectrometer at 80 MHz. The IR spectra were obtained on a Specord IR-75 instrument in thin layers.

• Research Organization: M. A. Suslov Rostov State Univ., USSR
• OSTI ID: 6036320
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:6; ISSN JOCYA
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
ALKENES
CHEMICAL SHIFT
COMPLEXES
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
CYCLOALKENES
DIENES
ENERGY
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
LINE BROADENING
LINE WIDTHS
LITHIUM COMPOUNDS
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYENES
SELENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS