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Title: Electroosmotically enhanced dewatering/deliquoring of fine-particle coal

Technical Report ·
DOI:https://doi.org/10.2172/6035842· OSTI ID:6035842

This research is an investigation of the use of electroosmosis to dewater/deliquor ultrafine coal. Post-beneficiation dewatering/deliquoring methods for ultrafine coals are inadequate and generally require subsequent thermal drying. The first year of this project focused on preparation of ultrafine coal samples, development of test equipment and test cells, identification of variables affecting electroosmosis, and trial runs. The second and final year was primarily devoted to the electroosmotic dewatering behavior of ultrafine coal. New measurement systems were developed, including a computer-controlled measurement system capable of measuring flow rates as low as 1 {mu}m per second. Furthermore, the effects of gravity, filter attenuation, voltage gradients, electrolysis, and temperature could be either determined explicitly or eliminated as a variable with these systems. Four of the more surprising contributions of this research are: (a) the observation of reversal of electroosmotic flow direction for coal; (b) strong evidence that the primary cause of high-voltage gradients in the coal near the cathode are attributable to reduced conductivity rather than due to trapped hydrolysis-produced hydrogen bubbles; (c) the observation of electroosmotic transport ratios (the ratio of uncharged water molecules removed per single ion removed) sufficiently large to demonstrate that the cost of actual electroosmotic transport of water through ultrafine coal can be very small; and (d) strong evidence that electroosmotic volume flow rates are very insensitive to temperature changes. 10 refs., 5 figs., 9 tabs.

Research Organization:
Southern Illinois Univ., Carbondale, IL (USA)
Sponsoring Organization:
USDOE; USDOE, Washington, DC (USA)
DOE Contract Number:
FC22-89PC89904
OSTI ID:
6035842
Report Number(s):
DOE/PC/89904-T22; ON: DE91011299
Country of Publication:
United States
Language:
English