New data on the reaction of 1,3-diaryl-3-(2-oxocyclohexyl)-1-propanones with hydrogen sulfide and methanol

Journal Article · Fri Feb 28 23:00:00 EST 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

OSTI ID:6033907

Klimenko, S K; Tyrina, T I; Stolbova, T V; Sorokin, N N; Kharchenko, V G

The stereochemical aspects of the reaction of 1-aryl- and 1,3-diaryl-substituted 3-(2-oxo-cyclohexyl)-1-propanones with hydrogen sulfide and methanol have been discussed. A mechanism is proposed for the formation of trans, trans-1-methoxy-3,5-diaryl-2-thia(oxa)bicyclo-(4.4.0)dec-3-enes.

• Research Organization: N.G. Chernyshevskii Saratov State Univ., USSR
• OSTI ID: 6033907
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:9; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKENES
CARBON 13
CARBON ISOTOPES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
COHERENT SCATTERING
CYCLOALKENES
DIFFRACTION
ENERGY
EVEN-ODD NUCLEI
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ISOMERIZATION
ISOMERS
ISOTOPES
KETONES
KINETICS
LIGHT NUCLEI
METHANOL
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PERCHLORIC ACID
REACTION KINETICS
SCATTERING
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
ULTRAVIOLET SPECTRA
X-RAY DIFFRACTION
YIELDS