Synthetic investigations in the chemistry of polyene compounds. XLIX. Synthesis of rac-(2E,4E)-3-methyl-5-(2,6-dimethyl-6-ethoxycarbonyl-3-oxo-1-cyclohexenyl)-2,4-pentadienal and rac-(2E,4E,6E)-5-methyl-7-(2,6-dimethyl-6-6-ethoxycarbonyl-3-oxo-1-cyclohexenyl)-2,4,6-heptatrienal and their derivatives with dimedone

Journal Article · Fri Jan 10 00:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6033769

Zhidkova, T A; Stashina, G A; Bogdanov, V S; Vakulova, L A; Samokhvalov, G I

The stereospecific synthesis of the previously unknown retinoids (C/sub 15/ and C/sub 17/ aldehydes) rac-(2E,4E)-3-methyl-5-(2,6-dimethyl-6-ethoxycarbonyl-3-oxo-1-cyclohexenyl)-2,4-pentadienal and rac-(2E,4E,6E)-5-methyl-7-(2,6-dimethyl-6-ethoxycarbonyl-3-oxo-1-cyclohexenyl)-2,4,6-heptatrienal and their derivatives with dimedone was realized in order to study their biological activity.

• Research Organization: Scientific-Production Society Vitaminy, Moscow, USSR
• OSTI ID: 6033769
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 21:8; Other Information: Translated from Zh. Org. Khim.; 21: No.8, 1653-1658(Aug 1985)
• Country of Publication: United States
• Language: English

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