Structural and physical studies on a new class of low-dimensional conducting material: FeOCl intercalated with TTF and related molecules
Conference
·
OSTI ID:6033735
Intercalation of TTF (tetrathiafulvalene), TTN (tetrathianaphthalene), and related organosulfur electron donors into FeOCl results in a significant expansion along the interlayer (b) axis, with the organosulfur molecules apparently inclined with respect to this axis. Electronic spectra suggest that the intercalates are semiconductors with band gaps of ca. 0.4 - 0.5 eV, consistent with previous conductivity data. Elastic neutron diffraction data (10/sup 0/K) show that magnetic ordering of the FeOCl host is abolished upon intercalation. 11 references, 1 figure, 1 table.
- Research Organization:
- Argonne National Lab., IL (USA)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6033735
- Report Number(s):
- CONF-8406192-2; ON: DE85009701
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTROSCOPY
ALKALI METAL COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
ELECTRIC CONDUCTIVITY
ELECTRIC CONDUCTORS
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
INFORMATION
INFRARED SPECTRA
IRON CHLORIDES
IRON COMPOUNDS
IRON OXIDES
LATTICE PARAMETERS
MATERIALS
MEDIUM TEMPERATURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
POTASSIUM BROMIDES
POTASSIUM COMPOUNDS
SEMICONDUCTOR MATERIALS
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPOUNDS
TTF
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTROSCOPY
ALKALI METAL COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
ELECTRIC CONDUCTIVITY
ELECTRIC CONDUCTORS
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
INFORMATION
INFRARED SPECTRA
IRON CHLORIDES
IRON COMPOUNDS
IRON OXIDES
LATTICE PARAMETERS
MATERIALS
MEDIUM TEMPERATURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
POTASSIUM BROMIDES
POTASSIUM COMPOUNDS
SEMICONDUCTOR MATERIALS
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENT COMPOUNDS
TTF